Date of Completion
5-2007
Degree Type
Honors Thesis - Campus Access
Discipline
Chemistry (CHEM)
First Advisor
Tina Choe
Abstract
The photochemical decarbonylation reaction of ketones has been the focus of much interest. The mechanism of this reaction involves the loss of CO by a sequential cleavage of two sigma bonds. Our group is interested in developing the solid-state photodecarbonylation reaction to synthesize complex bicyclic compounds from the corresponding bridged ketones. The bridged ketones were synthesized using a tandem Michael-addition-intramolecular aldolization and Mn(III) based oxidative free radical cyclization.
Recommended Citation
Welch, Barrett Michael Warren, "A Synthesis of Bridged Ketones to Study the Photochemical Decarbonylation Reaction" (2007). Honors Thesis. 248.
https://digitalcommons.lmu.edu/honors-thesis/248