Date of Completion

5-2007

Degree Type

Honors Thesis - Campus Access

Discipline

Chemistry (CHEM)

First Advisor

Tina Choe

Abstract

The photochemical decarbonylation reaction of ketones has been the focus of much interest. The mechanism of this reaction involves the loss of CO by a sequential cleavage of two sigma bonds. Our group is interested in developing the solid-state photodecarbonylation reaction to synthesize complex bicyclic compounds from the corresponding bridged ketones. The bridged ketones were synthesized using a tandem Michael-addition-intramolecular aldolization and Mn(III) based oxidative free radical cyclization.

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